Hesam Omrani Fard; Mohammad Hossein Abaspour fard; Mehdi Khojastehpour; Ali Dashti
Abstract
Introduction: One of the new methods for improving the mechanical properties of bioplastics is the production of blending based bioplastics. Recent studies show that proteins, in combination with starch, form a strong network of hydrogen bonds and intermolecular interactions that resulted stable 3-D ...
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Introduction: One of the new methods for improving the mechanical properties of bioplastics is the production of blending based bioplastics. Recent studies show that proteins, in combination with starch, form a strong network of hydrogen bonds and intermolecular interactions that resulted stable 3-D materials. The big problem in the commercialization of blending based bioplastics is the lack of industrial machinery for the continuous production of bioplastics with the direct use of biopolymers. Industrial production of bioplastics is accompanied by increasing heat along with applying the pressure. It is necessary to know the kinetics of thermal degradation of bioplastics to study thermal behavior at different temperatures in order to design bioplastics processing devices and molding machines, software modeling of processes, mass and energy equilibrium, and optimizing energy consumption in the production process along with improving the thermal properties of the bioplastics.
Materials and methods: In this study, the dynamics thermal decomposition of bioplastics prepared from a mixture of potato whole flour-gelatin and glycerol with a control sample consisting of potato whole flour and glycerol was investigated and compared. The gelatin was extracted from chicken feet using chemical methods. In this research, two isoconversional models including Flynn-Wall-Ozawa (FWO) and Kissinger-Akahira-Sunose (KAS) models were considered. Using each of these models, thermal decomposition kinetic parameters were calculated for bioplastic samples.
Result and discussion: The results showed that the maximum activation energy of the mixed bioplastics determined 162 and 150 kJ/mol by FWO method at the conversion ratio of 0.9 and 0.5 respectively, while it was 217 kJ/mol at the ratio of 0.6 for control bioplastics. The amounts of kinetic parameters calculated in this study, were able to determine the thermal behavior at different temperatures and the thermal decomposition process. Also, it can help to redesign and optimize the methods of molding and shaping of potato-gelatin based bioplastics by the use of existing machinery in the industry.
Adieh Anvar; Behzad Nasehi; Mohammad Noshad; Hassan Barzegar
Abstract
In this study, microwave drying conditions of quince pomace optimized with respect to quality attributes (moisture content, color change and consumer acceptance). Response surface methodology (RSM) technique was used to develop models to respond to the microwave power (100, 2000, 300 W), and microwave ...
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In this study, microwave drying conditions of quince pomace optimized with respect to quality attributes (moisture content, color change and consumer acceptance). Response surface methodology (RSM) technique was used to develop models to respond to the microwave power (100, 2000, 300 W), and microwave time (5, 10, 15 min). The models obtained from the responses were adequate and acceptable because the coefficient of determination R2 of the models was relatively high. Microwave power of 200W and microwave time of 8 minutes were concluded as the optimum conditions prior to air-drying at 50°C. To describe the drying process, the experimental data for moisture loss was converted to moisture ratios. The effective moisture diffusivity increased with increase in microwave power and its values varied from 1.83-4.87×10-9 m2/s. Using an exponential expression based on Arrhenius equation the activation energy and was found to be 16.41 W/mm.
Amir Salari; Mostafa Mazaheri Tehrani; Seyed Mohammad Ali Razavi
Abstract
In this study, mathematical modeling of hot air baking-drying of thin-layer crisp bread was investigated. Thin-layer drying process were conducted under three different temperatures of 110, 150 and 190 °C at a constant air velocity of 0.5±0.1 m/s and absolute humidity of 0.6 ± 0.04g ...
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In this study, mathematical modeling of hot air baking-drying of thin-layer crisp bread was investigated. Thin-layer drying process were conducted under three different temperatures of 110, 150 and 190 °C at a constant air velocity of 0.5±0.1 m/s and absolute humidity of 0.6 ± 0.04g water/kg dry air. It was found that the baking-drying process occurred in falling rate period over the baking-drying times. Eight well-known thin-layer baking-drying models were fitted to the baking-drying experimental data of crisp bread, implementing non-linear regression analysis techniques. Based on the coefficient of determination (R²) and root mean square error (RMSE) values, it was concluded that the best models in terms of fitting performance for hot air baking-drying of bran free crisp bread were Wang & Singh and Logarithmic while for whole-wheat crisp bread were Page, Logarithmic and Wang & Singh. The moisture transfer from crisp bread was described using the Fick’s diffusion model. The effective diffusivity was within the range of 2.88×10-8 to 1.11×10-7 m2/s for bran free crisp bread and from 2.47×10-8 to 8.84×10-8 m2/s for whole-wheat crisp bread over the temperature range. The activation energy for bran free and whole-wheat crisp bread was found to be 25.22 and 23.43 kJ/mol, respectively..
Farideh Tabatabaei Yazdi; Mohebbat Mohebbi; Seyed Ali Mortazavi; Arash Ghaitaranpour; Behrooz Alizadeh Behbahani
Abstract
The effects of a couple of factors (cooking period of wheat: 0, 1 and 3.5 h and temperature of drying 70, 80 and 90 ْC) on drying behavior of Tarkhineh during hot-air drying has been investigated. Tarkhineh pill samples with 8 cm diameter and 11 mm thickness were dried to 0.64(d.b). Results showed that ...
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The effects of a couple of factors (cooking period of wheat: 0, 1 and 3.5 h and temperature of drying 70, 80 and 90 ْC) on drying behavior of Tarkhineh during hot-air drying has been investigated. Tarkhineh pill samples with 8 cm diameter and 11 mm thickness were dried to 0.64(d.b). Results showed that cooking of wheat led to higher water absorption of Tarkhineh dough, while increased drying rate. On the other hand, increasing drying temperature resulted in higher drying rate of samples. The effects of temperature on drying rate was pronounced in raw samples compared to cooked ones, which could be attributed to the cracking in the cooked samples during drying . Drying kinetics of Tarkhineh in raw samples unlike cooked samples presented a falling rate period followed by a constant rate period. The effective moisture diffusion coefficient of Tarkhineh varied between 1.611E-10 & 7.822E-10 (m2/s)) for the given temperature range) and corresponding activation energy was between 37.928 and 17.941(kJ/mol) respectively.
