Food Technology
Hosein Ghavami; Azin Nasrollah zadeh
Abstract
Introduction All the different species of hazelnut trees produce edible nuts. Hazelnuts are one of the most nutritious nuts, with a protein content of about 12%. They are also a good source of energy, with a fat content of about 60%, and an excellent source of carbohydrates, half of which are dietary ...
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Introduction All the different species of hazelnut trees produce edible nuts. Hazelnuts are one of the most nutritious nuts, with a protein content of about 12%. They are also a good source of energy, with a fat content of about 60%, and an excellent source of carbohydrates, half of which are dietary fiber. Hazelnuts also contain minerals (Ca, Mg, P, K), vitamins (E and B), and antioxidants. Hazelnut kernels may be eaten raw or roasted. Roasting alters and significantly enhances the color, texture, and appearance of nuts. These changes increase the overall palatability of the nuts and are mainly related to non-enzymatic browning. Non-enzymatic browning, however, causes a decrease in nutritional value due to decrease in protein digestibility and loss of essential amino acids. The most widely used nut roasting method is the convective heat transfer process, which is performed in a hot air oven working either in continuous mode or in batch systems. Therefore, modifying this process for improving product quality is very important. Color is among the most important quality attributes of dehydrated foods for consumers. Empirically, color is also an effective quality indicator because the brown pigments increase as the browning and caramelization reactions progress. Therefore, this study aimed to investigate the effect of high roasting temperature and storage time on color changes and oxidation of hazelnut paste oil. Materials and Methods After getting hazelnut kernels, the Roasting process was performed with hot air at 130 and 170 ℃ for 20 minutes. Hazelnut paste is produced as practiced in the industry. Quality analysis was roasted hazelnut paste color changes and fat oxidation. L *, a *, b * color index, (∆E), acidity, and peroxide value were measured in three intervals (0, 10, 30 days’). All experiments were performed in three replications. Average Data was compared using one-way ANOVA and done by SPSS version 21. Results and Discussion The main purpose of roasting is to improve the flavor, the color, and the crispy and crunchy texture of the product. The roasting process is very important to determine the characteristic roasted flavor and color of the product: in particular, temperature modulation is an important independent variable significantly affecting the quality features of hazelnut. In this study, ANOVA analysis results showed a significant difference between the treatments. Both roasting temperature and storage time affect the acidity and peroxide value. The increased temperature and storage increased the acidity and peroxide index, which indicated fat oxidation at higher temperatures. For ten days, the sample's peroxide value increased. After that, these parameters decreased because the first autoxidation products changing to the second product. Due to the release of free fatty acids after the basic hydrolysis of triglycerides, the acidity of the samples increased. The Browning color of roasted products was desirable. Discoloration during the roasting process of hazelnut kernels is mainly related to non-enzymatic browning. The brown pigments increase with the development of browning reactions. Results showed that the color index includes the L*, a*, b*, and ∆E values of the samples only affected by roasting temperature. With increasing the temperature, the L* value decreased but other values increased. Color indicators significantly changed and are not desirable for the consumers. The rate of color changes increased, including browning, indicating a non-enzymatic browning reaction in the samples during roasting. ConclusionAccording to the results, hazelnuts roasted at 130℃ introduced as the best treatment. It is recommended that the storage time does not exceed ten days.
Reza Farahmandfar; Somayeh Salmani; Hoda Fahim
Abstract
Introductıon: Nuts are one of the major resources of bioactive compounds such as tocopherols, tocotrienols, sterols (Jensen and Lauridsen, 2007). Tocopherols include 8 natural homologues that all of them belongs to vitamin E group (Chun, 2002). It is well known that vitamin E has good antioxidant activity ...
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Introductıon: Nuts are one of the major resources of bioactive compounds such as tocopherols, tocotrienols, sterols (Jensen and Lauridsen, 2007). Tocopherols include 8 natural homologues that all of them belongs to vitamin E group (Chun, 2002). It is well known that vitamin E has good antioxidant activity and among its isomers, α-tocopherol and γ-tocopherol have highest biological activity and free radical scavenging, respectively (Grilo et al., 2014). In recent years, the beneficial health effects of vitamin E on some disease such as cancer and heart disorders attract researcher’s attentions (Wagner et al., 2004).Roasting process changes the chemical and nutritional properties of nuts, including antioxidants, vitamins, colors, and aroma mostly through Maillard reaction (Alamprese et al., 2009; Ballistreri et al., 2009). Due to the importance of vitamin E antioxidant activity and its heat sensitivity, the residual amounts of them after different roasting conditions were investigated. Materials and methods: Samples were spreaded in alominum foil and placed in forced air oven at 120 and 150 ºC and different time intervals including 0, 20, 30 and 40 min. After roasting, samples were powdered, then 0.5 g of each sample plus 0.05 g ascorbic acid were added to 0.5 mL ethanol (90.2%) and 0.5 mL KOH and mixed in a tube (16× 125 mm). The tube was then placed in water bath for 30 min. Then, the tube were placed in ice bath for 5 min, then 3 mL deionized water, 5 mL hexane were added to the tube and vortexed for 30 s and centrifuged for 10 min at 1000 rad/s at ambient temperature. The extraction was done twice. Hexane layer evaporated with nitrogen then 1 mL of mobile phase added to tube and vortexed again. Prepared samples then were injected to HPLC (Knuer- Germany). Results and discusion: Based on the obtained results, α-tocopherol content in almond was more than γ-tocopherol. After 20 and 30 min of roasting, at 150 and 120 ºC respectively, the amount of α-tocopherol slightly increased, while it decreased with increasing roasting time. γ-tocopherol content in almond at both temperatures also increased up to 20 min roasting and decreased till the end of process. In hazelnut, at both temperatures up to 20 min and then decreased till end of roasting process. This trend was shown for peanut tocopherols as well. With increasing in roasting time, α-tocopherol and γ-tocopherol content decreased to their initial level. It has suggested that tocopherols which attached to the other components such as phospholipids released more conveniently under thermal treatment like roasting which leads to increase their concentrations at initial of thermal process. In pistachio, 150 and 120 ºC respectively caused to increase in γ-tocopherol content, respectively while its content decreased up to the end of roasting time (40 min). α-tocopherol content at both temperatures increased after 20 min, then decreased gradually as time passes. Results indicated that both time and temperature of roasting had a significant effect on α- and γ-tocopherol of four nuts. Although both of temperatures in our study significantly on increased vitamin E isomers at the start of roasting process, their contents decreased with increasing in roasting time. Maximum amount of both isomers were detected at 120 ºC after 30 min and at 150 ºC after 20 min.
