با همکاری انجمن علوم و صنایع غذایی ایران

نوع مقاله : مقاله پژوهشی

نویسندگان

دانشگاه علوم کشاورزی و منابع طبیعی ساری

چکیده

آلودگی ناشی از استفاده از مواد پلاستیکی سنتزی موجب نگرانی علاقمندان به محیط زیست شده است. این امر پژوهشگران را به تحقیق بر روی بیو پلیمر ها به منظور استفاده در صنایع بسته بندی وا داشته است. مقاومت ضعیف در برابر رطوبت مهمترین نقص آن ها می باشد. فیلم های خوراکی از نشاسته واکسی با مقادیر متفاوتی از اسید سیتریک یا متیل سلولز به روش مرطوب تهیه شدند. تأثیر افزایش اسید سیتریک و متیل سلولز بر روی خواص فیزیکی فیلم ها شامل نفوذ پذیری نسبت به بخارآب واکسیژن و خواص مکانیکی فیلم ها شامل مقاومت کششی، درصد ازدیاد طول تا نقطه پارگی و مدول الاستیک مورد بررسی قرار گرفتند. نفوذ پذیری آن ها نسبت به بخار آب (WVP) با استفاده از روش مهاجرت رطوبت از فنجانک ها اندازه گیری شدند. سرعت مهاجرت اکسیژن ((OTR از طریق اندازه گیری عدد پراکسید روغن موجود در فنجانک ها اندازه گیری شدند. خواص مکانیکی فیلم ها با استفاده از دستگاه کشش اندازه گیری شدند. افزدون اسید سیتریک تا 5 درصد موجب کاهش نفوذ پذیری به بخار آب و اکسیژن شد. فیلم حاوی 5 درصد (وزنی/ وزنی) اسید سیتریک، کمترین WVP را نشان داد، در حالیکه با افزایش اسید سیتریک به میزان 20 درصد موجب افزایش نفوذ پذیری به بخار آب و ازدیاد طول فیلم ها تا نقطه پارگی و کاهش مقاومت کششی فیلم هاگردید. افزدون متیل سلولز تا 30 درصد (وزنی/ وزنی) نفوذ پذیری به بخار آب و اکسی‍ژن را کاهش داد.

کلیدواژه‌ها

عنوان مقاله [English]

Studies on Different Properties of Composite Thin Films Made from Waxy Starch-citric acid and Starch-methyl Cellulose

نویسندگان [English]

  • Abdolhossien Aghababaei
  • Reza Kasaai

Sari Agricultural Sciences and Natural Resources University

چکیده [English]

Pollution arising from plastic waste materials caused a great worry for researchers who are interested in protection of environment. This problem shifts their subject to bio-polymers for applications in packaging industries. However, their low water barrier properties are a critical problem. The effects of citric acid and methyl cellulose on water vapor and oxygen permeabilities and mechanical properties of starch composite thin films have been studied. Water vapor permeability (WVP) has been measured using a vial coated by a film. Oxygen transmission rate (OTR) of a film was determined from measurement of peroxide value for a definite amount of oil that is placed in a vial and coated by the film. Mechanical properties were measured using a tensile machine. Increase in citric acid concentration up to 5% citric acid (w/w), resulted in a decrease in water vapor and oxygen permeabilities. A film containing 5% of citric acid exhibited a minimum value for WVP, whereas the value of WVP and elongation at the break increased and tensile strength decreased for a film containing 20% of citric acid (w/w). Increase in methyl cellulose up to 30% resulted in decrease in WVP and OTR.

کلیدواژه‌ها [English]

  • Waxy Starch
  • Citric acid
  • Methylcellulose
  • Water Vapor permeability
  • Mechanical properties
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