بررسی پتانسیل زغال فعال تولیدی از پوست انار به‌عنوان جاذب رنگ و فلزات دو و سه‌ ظرفیتی در محیط‌های مایع

نوع مقاله : مقاله پژوهشی

نویسندگان

• نرگس هادی گل ¹
• مریم فهیم دانش ¹
• سپیده حسینی ²

¹ گروه علوم و صنایع غذایی، واحد شهر قدس، دانشگاه آزاد اسلامی، تهران، ایران.

² باشگاه پژوهشگران جوان، واحد شهر قدس، دانشگاه آزاد اسلامی، تهران، ایران.

https://doi.org/10.22067/ifstrj.v15i4.68925

چکیده

پوست انار یکی از منابع مهم ترکیبات زیست فعال بوده که توانایی بالایی در جایگزینی منبع زغال فعال مناسب برای جذب فلزات سنگین و رنگ‌بری در محیط مایع دارد. هدف از این تحقیق بررسی توانایی پوست انار در کاهش غلظت فلزات سنگین موجود در آب و روغن و همچنین ارزیابی عملکرد رنگ‌بری روغن آن است. در مرحله اول تحقیق شرایط جذب یون‌های فلزی در محیط آبی بهینه‌سازی گردید به‌این‌ترتیب که سه متغیر مستقل pH (X1)، زمان مجاورت ماده جاذب و فلزات (X2)  و غلظت ماده جاذب در محیط آبی (X3) بر درصد جذب یون‌های آهن و کروم (متغیرهای وابسته) بر اساس طرح باکس- بانکن بررسی شد. نتایج نشان داد که بیشترین جذب فلزات در شرایط 3/5=pH، در زمان 200 دقیقه و غلظت ماده جاذب 5/2 گرم در لیتر روی می‌دهد. در شرایط بهینه جذب فلزات سنگین سرب، جیوه و آرسنیک نیز مورد ارزیابی قرار گرفت و نتایج نشان داد که جاذب باعث کاهش 80 درصدی این یون‌ها می‌شود. در مرحله بعد توانایی رنگ‌بری و کاهش فلزات سنگین زغال فعال تولیدی در محیط روغن موردبررسی قرار گرفت. نتایج نشان داد این جاذب توانایی خوبی برای رنگ‌بری و پایداری اکسیداسیون روغن دارد. در رابطه با کاهش فلزات سنگین روغن نیز ماده جاذب تولیدشده از پوست انار عملکرد بهتری نسبت به خاک رنگ‌بر تجاری نشان داد.

کلیدواژه‌ها

• پوست انار
• ماده جذب شونده
• جاذب
• فلزات سنگین
• کروم، سرب
• آهن

عنوان مقاله [English]

Evaluation of pomegranate peel carbon potential as a adsorbent of pigment and bi and trivalent metals in liquid media

نویسندگان [English]

• Narges Hadigol ¹
• Maryam Fahim danesh ¹
• Sepideh Hoseini ²

¹ Department of Food Science and Technology, Shahr-e-Qods Branch, Islamic Azad University-Tehran- Iran.

² Department of Food Science and Technology, Shahr-e-Qods Branch, Islamic Azad University-Tehran- Iran.

چکیده [English]

Introduction: Pomegranate peel is an important source of bioactive compounds which have high potential of alternative source of activated carbon for bleaching and the removal of heavy metal from liquid media. The present study was undertaken to evaluate the feasibility of pomegranate peel carbon for the removal of heavy metal from oil and aqueous solution and then to investigate its activity in the bleaching of sesame oil.
 
Materials and methods: Response surface methodology and Box-Behnken design were applied to study and optimize the adsorption condition to remove metal ions on prepared pomegranate peel adsorbent. For this purpose, the effects of three independent variable pH(X1), contact time (X2) and adsorbent dose (X3) on metal ions concentration (dependent variable) were studied using a three-level three-factor Box–Behnken design. In addition, different types of adsorbents (pomegranate peel carbon and activated earth) were tested for adsorption of pigment, peroxides and heavy metals of sesame oil.
 
Results and discussion: Results showed that optimum condition required for maximum adsorption were found to pH= 5.3, equilibrium time 200 min and adsorbent concentration 2.5 g/L. Under the optimal conditions the removal of heavy metals i.e. Fe, Cr, Pb, as and Hg from aqueous solution by activated carbon developed from pomegranate peel are more than 80%. Results of sesame oil bleaching with pomegranate peel carbon showed good bleaching efficiency and oxidative stability. Furthermore, pomegranate peel carbon comparing with bleaching earth showed better ability to decrease heavy metal content of oil.
 

کلیدواژه‌ها [English]

• Adsorbatey
• Adsorbent
• Chromium
• Heavy metals
• Lead
• Pomegranate Peel
• Iron

مراجع

جهرمی، م.، نیاکوثری، م.، شریفی، ا .، کلانتری، م.،( 1393). بررسی ویژگی‌های فیزیکی و شیمیایی پودرهای شیره انگور و خرما و عصاره انجیر خشک‌شده در یک خشک‌کن غلتکی. نشریه‌ی نوآوری در علوم و فنّاوری غذایی، 7 (3)، 93-85.

مهریزی، ر.، امام‌جمعه، ز.، شاهدی، م.، لونی، ا.، اخوان، ح.، بیابانی، ج.، (1394) . شناسایی کمی و کیفی آنتوسیانین ها در عصاره پوست انار، فصلنامه علوم و صنایع غذایی، 49، 52-59.

Abedi, E., Sahari, M.A. Barzegar, M., & Hossein Azizi, M., 2015, Optimisation of soya bean oil bleaching by ultrasonic processingand investigate the physico-chemical properties of bleached soyabean oil. International Journal of Food Science and Technology, 50, 857–863.

Afaq, F., Saleem, M., Krueger, C.G., Reed, J.D. & Mukhtar, H, 2005, Anthocyanin and hydrolyzable tannin-rich pomegranate fruit extract modulates MAPK and NF-kappaB pathways and inhibits skin tumorigenesis in CD-1 mice. International Journal of Cancer, 113, 423–433.

Alam, M., Nadeem, R. & Idress Jilani, M., 2012, Pb (II) removal from wastewater using Pomegranate waste biomass. International Journal of Chemical and Biochemical Sciences, 1, 24-29.

Angelova, V., Ivanova, R., adka, b. & Ivanov, K., 2005, Heavy Metal Accumulation and Distribution in Oil Crops. Communications in Soil Science and Plant Analysis, 35, 2551-2566.

AOAC, 2016, official methods of analysis of aoac international 20th edition. Association of Official Agricultural Chemists.

AOCS, 2007, Official methods and recommended practices of the American Oil Chemists’ Society. Champaign, Ill, AOCS.

Aviram, M., Dornfeld, L., Rosenblat, M., Volkova, N., Kaplan, M., Coleman, R. & Hayek, T., 2008, Pomegranate juice consumption reduces oxidativ stress, atherogenic modifications to LDL, and platelet aggregation: studies in humans and in atherosclerotic apolipoprotein E-deficient mice. American Journal of Clinical Nutrition, 51, 76-79.

Aviram, M., Volkova, N., Coleman, R., Dreher, M., Reddy, M.K., Ferreira, D. & Rosenblat, M., 2008, Pomegranate phenolics from the peels, arils, and flowers are antiatherogenic: studies in vivo in atherosclerotic apolipoprotein e-defi- cient (E 0) mice and in vitro in cultured macrophages and lipoproteins. Journal of Agricultural and Food Chemistry, 56, 1148–1157.

Bansal, R.C. & Goyal, M., 2005, Activated Carbon Adsorption. CRC Press, Taylor & Francis Group, LLC, Boca Raton, 128-132.

Bhatnagar, A. & Minocha, A.K., 2010, Biosorption optimization of nickel removal from water using Punica granatum peel waste. Biointerfaces, 76, 544–548.

Celik, I., Temur, A. & Isik, I., 2009, Hepato protective role and antioxidant capacity of pomegranate (Punica granatum) flowers infusion against tri chloro acetic acid- exposed in rats. Food and Chemical Toxicology, 47,145–149.

Choe, EO & Moon, SY., 1994. Effects of filtration or centrifugation on the oxidative stabilities of sesame oil. Agricultural chemistry & biotechnology, 37,168–74.

Coswami, S. & Ghosh, U.C., 2005, Studies on adsorption behavior of Cr (VI) onto synthetic hydrous stannic oxide. Water SA, 31, 597–602.

El-Ashtoukhy, E., Amin, N. & Abdelwahab, O., 2008, Removal of lead (II) and copper (II) from aqueous solution using pomegranate peel as a new adsorbent. Desalination, 223, 162–173.

El-Nemr, A., 2009, Potential of pomegranate husk carbon for Cr (VI) removal from wastewater: Kinetic and isotherm studies. Journal of Hazardous aterials, 16, 1132- 1141.

Ganesan, V., Rosentrater, K. A. and Muthukumarappan, K., 2008, Flowability and handling characteristics of bulk solids and powders – a review with implications for DDGS. Biosystems Engineering, 101, 425-435.

Hussin F, Kheireddin M. & Wandaud W., 2001, Textural Characteristics, Surface Chemistry and Activation of Bleaching Earth. Journal of Chemical Engineering, 170, 90- 106.

IUPAC, 1998, Standard Method-Oil – Scribd of International Union of Pure and Applied Chemistry.

Kaynak G, Ersoz M & Kara H., 2004, Investigation of the Properties of Oil at The Bleaching Unit Of an Oil Refinery. Journal of Colloid and Interface Science, 280, 131-138.

Kim, I. & Choe, E., 2005, Effects of Bleaching on the Properties of Roasted Sesame Oil. Journal of Food Science, 70, 48-52.

Low, K.S., Lee, C.K. & Lee, K.P., 1993, Sorption of copper by dye-treated oil-palm fibers. Bioresource Technology, 44, 109–112.

Lu, J., Yuan, Q., 2008. A new method for ellagic acid production from pomegranate husk. Journal of Food Process Engineering 31, 443–454.

Malkoc, E. & Nuhoglu, Y., 2003, The removal of chromium (VI) from synthetic wastewater by Ulothrix zonata, Fresenius Environmental Bulletin, 12 (4), 361–376.

Marrakchi, F., Bouaziz, M. & Hameed B.H., 2017, Activated carbon–clay composite as an effective adsorbent from the spent bleaching sorbent of olive pomace oil: Process optimization and adsorption of acid blue 29 and methylene blue. Chemical Engineering Research and Design, 53, 88-91.

Mestre, A.S., Bexiga, A.S., Proença, M., Andrade, M., Pinto, M.L., Matos, I., Fonseca, I.M. & Carvalho, A.P., 2011, Activated carbons from sisal waste by chemical activation with K2CO3: Kinetics of paracetamol and ibuprofen removal from aqueous solution. Bioresource Technology, 102, 8253–260.

Morgan, B. & Lahav, O., 2007, the effect of pH on the kinetics of spontaneous Fe (II) oxidation by O2 in aqueous solution – basic principles and a simple heuristic description. Chemosphere, 68, 2080–2084.

Pai, V., Chanu, T.R., Chakraborty, R., Raju, B., Lobo, R. & Ballal, M., 2011, Evaluation of theantimicrobialactivityof Punica granatum peel againsttheenteric pathogens: aninvitrostudy. Asian Journal of Plant Science and Researc, 42, 57-62.

Pillai, M.G., Regupathi, I., Kalavathy, M.H., Murugesan, T. & Miranda, L.R., 2009, Removal of hazardous heavy metals from aqueous environment by low-cost adsorption materials. Journal of Chemical and Technological Biotechnology, 84, 291-296.

Pino, G.H., de Mesquita, L.M.S., Torem, M.L. & Pinto, G.A.S., 2006, Biosorption of cadmium by green coconut shell powder. Mining Engineering, 32, 77-81.

Saeed, A., Akhter, M.W. & Iqbal, M., 2005, Removal and recovery of heavy metals from aqueous solution using papaya wood as a new biosorbent, Purification Technologies, 45, 25–31.

Seeram, N.P., Lee, R. & Heber, D., 2004, Bioavailability of ellagic acid in human plasma after consumption of ellagitannins from pomegranate (Punica granatum L.) juice. Clinica Chimica Acta; International Journal of Clinical Chemistry, 348, 63–68.

Skevin, D., Domijan, T., Kralji, K., Gajdo, J., Neleral, S., and Obranovi, M., 2012, Optimization of Bleaching Parameters for Soybean Oil. Food Technology and Biotechnology, 50 (2), 199–207.

Spiteri, C., Regnier, P., Slomp, C.P., & Charette, M.A. (2006). pH- dependent iron oxide precipitation in a subterranean estuary. Journal of Geochemical Exploration, 88, 399–403.

Tang J., Mu B., Maosung Z. & Wang A., 2015, One-Step Calcination of the Spent Bleaching Earth for the Efficient Removal of Heavy Metal Ions. ACS Sustainable Chemistry & Engineering, 39, 115-119.

Zahin, M., Aqil, F. & Ahmad, I., 2010, Broad spectrum antimutagenic activity of antioxidant active fraction of Punica granatum L. peelextracts. Mutation Research, 703, 99–107.

Zhu, F., Fan, W., Wang, X., Qub, L. & Yao, S., 2011, Health risk assessment of eight heavy metals in nine varieties of edible vegetable oils consumed in China. Food and Chemical Toxicology, 49 3, 081–3085.