با همکاری انجمن علوم و صنایع غذایی ایران

نوع مقاله : مقاله پژوهشی

نویسندگان

گروه علوم و صنایع غذایی، دانشکده کشاورزی، دانشگاه فردوسی مشهد، مشهد، ایران.

چکیده

پایداری اکسایشی روغن کانولا تحت تاثیر روغن مغز بنه طی 48 ساعت سرخ کردن در دمای 180 درجه سانتیگراد در مقایسه با آنتی اکسیدان سنتزی ترسیو بوتیل هیدروکینون با اندازه گیری تغییرات مقدار کل ترکیبات قطبی و اجزاء تشکیل دهنده آن بررسی شد. مقدار کل ترکیبات قطبی در طول زمان سرخ کردن به صورت خطی افزایش پیدا کرد (ضریب تبیین بیش از 98/0). روغن مغز بنه و بویژه سطح 1/0 درصدی آن باعث افزایش پایداری روغن کانولا شد. ساختار ترکیبات قطبی با استفاده از کروماتوگرافی غربال ملکولی با کارایی بالا تعیین شد و اجزاء تشکیل دهنده آن شامل تری آسیل گلیسرولهای پلیمری، تری آسیل گلیسرولهای دیمری، تری آسیل گلیسرولهای اکسید شده، دی آسیل گلیسرولها و اسیدهای چرب آزاد نیز مورد ارزیابی قرار گرفت. توانایی روغن مغز بنه در ممانعت از تشکیل تری آسیل گلیسرولهای پلیمری و اکسید شده به ترسیو بوتیل هیدروکینون نزدیک بود، در حالی که توانایی آن در ممانعت از تشکیل دی آسیل گلیسرولها و اسیدهای چرب آزاد بمراتب بهتر از ترسیو بوتیل هیدرو کینون بود

کلیدواژه‌ها

عنوان مقاله [English]

Investigation on Polar Compounds Distribution of Canola Oil Using High-Performance Size-Exclusion Chromatography (HPSEC) as Affected by Bene Kernel Oil during Frying Process

نویسندگان [English]

  • Reza Farhoosh
  • Hashem Pourazerang
  • Mohammad Hossein Hadad Khodaparast

Department of Food Science and Technology, Ferdowsi University of Mashhad, Mashhad, Iran.

چکیده [English]

Measuring the rate of changes in total polar compounds (TPC) content and polar fractions, the oxidative stability of canola oil during frying process as affected by bene kernel oil (BKO, 0.05 and 0.1%) and tert-butylhydroquinone (TBHQ, 100ppm) was investigated. It was observed that the TPC content increased linearly with frying time (R2 > 0.98). The canola oil containing the BKO (especially 0.1%) was significantly capable of increasing oxidative stability. The TPC analysis by high-performance size-exclusion chromatography allowed the separation and quantification of triglyceride polymers (TGP), triglyceride dimers (TGD), oxidised triglyceride monomers (oxTGM), diglycerides (DG), and free fatty acids (FFA) during frying. The ability of the BKO to resist the TGP and oxTGM formations was near to that of the TBHQ, whereas the ability of the BKO to resist the DG and FFA formations was better than that of the TBHQ.

کلیدواژه‌ها [English]

  • Canola oil
  • Bene kernel oil
  • Thermo-oxidative and hydrolytic degradations
  • High-performance size-exclusion chromatography
  • Frying
  • Polar compounds
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